Soal dan jawaban cara menentukan hasil perhitungan menentukan derajad keasaman, pH suatu larutan asam dan larutan basa. Soal ini berlaku pada larutan asam kuat dan basa kuat, juga asam dan basa lemah.
- Tentukan harga pH larutan 0,01 M HCl
Jawab
HCl(aq) → H+(aq) + Cl-(aq)
[H+] = [HCl] = 0,001 M = 10-2 M
pH = -log [H+]
pH = -log 10-2
Jadi pH larutan = 2 - Berapa pH larutan 0,05 M H2SO4 ?
Jawab
H2SO4(aq) → 2H+(aq) + SO42-(aq)
Dari persamaan reaksi
[H+] = 2 x [H2SO4]
[H+] = 2 x 0,005 = 0,1 M = 10-1 M
pH = -log [H+]
pH = -log 10-1
pH = 1 - Berapa [H+] dalam larutan HNO3 yang pHnya 2 ?
Jawab
HNO3(aq) → H+(aq) + NO3-(aq)
pH = -log [H+]
2 = -log [H+]
log [H+] = -2
log [H+] = log 10-2
[H+] = 10-2 = 0,01 M - Tentukan pH larutan 0,01 M NaOH !
Jawab
NaOH(aq) → Na+(aq) + OH-(aq)
[OH-] = [NaOH]
[OH-] = 0,01 M = 10-2 M
pOH = -log [OH-]
pOH = -log 10-2
pOH = 2
pH = 14 – 2
pH = 12 - Berapa [OH-] yang terdapat dalam larutan KOH yang pHnya 13 ?
Jawab
KOH(aq) → K+(aq) + OH-(aq)
pH = 13
pOH = 14 – 13 = 1
pOH = -log [OH-]
1 = -log [OH-]
log [OH-] = -1
log [OH-] = log 10-1
[OH-] = 10-1 = 0,1 M - Tentukan pH larutan CH3COOH 0,1 M jika Ka CH3COOH = 1,8 x 10-5 !
Jawab
Ca = [CH3COOH] = 0,1 M = 10-1 M
[H+] = √(Ka.Ca
pH = - log [H+]
pH = - log 1,34.10-3
pH = 3 – log 1,34
pH = 3 – 0,137
pH = 2,873 - Berapa pH larutan amonia 0,1 M yang tetapan ionisasinya 1,7.10-5 ?
Jawab
NH3(g) + H2O(l) ⇄ NH4+(aq) + OH-(aq)
Cb = [NH3] = 0,1 M = 10-1 M
pOH = - log [OH-]
pOH = - loh 1,3 . 10-3
pOH = 3 – log 1,3
pOH = 3 – 0,114
pOH = 2,886
pH = 14 – pOH
pH = 14 – 2,886
pH = 11,114
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